Tetrakis (triphenylphosphine) palladium(0)

Tetrakis (triphenylphosphine) palladium(0)

Phân loại: Coupling ,Organometallic catalyst

Tính chất: HPLC

Thương hiệu: AKSci

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DENTITY  
CAS Number: 14221-01-3
MDL Number: MFCD00010012
MF: C72H60P4Pd
MW: 1155.56
EINECS: 238-086-9
BRN: 6704828
SPECIFICATIONS & PROPERTIES  
Min. Purity Spec: 98%
Physical Form (at 20°C): Solid
Melting Point: 100-107°C
Long-Term Storage: Store long-term at -20°C
Note: Packed under nitrogen.
: G983
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CHI TIẾT :

REVIEW
 A catalyst for coupling reactions such as the Heck, Suzuki, Negishi and Sonogashira cross-coupling reactions and Buckwald-Hartwig aminations (1-5). High yielding palladium-catalyzed reductive debromination of fused diporphyrins (6). A catalyst employed in arylation of sulfonamide stabilised enolates (7) and allylation of Meldrum's acids by allylic alcohols without prior activation of allylic hydroxy group (8).

REFERENCES

[1] Tetrahedron Lett. 1993, 34, 2813.
[2] J. Phys. Chem. C, 2008, 112, 10273.
[3] Adv. Synth. Catal. 2009, 351, 1727.
[4] Synthesis 2007, 1061.


GLOBALLY HARMONIZED SYSTEM (GHS)

Pictograms


Signal Word

Warning


Hazard Statements

H315; H319; H335


Precautionary Statements

P261; P264; P271; P280; P302+P352; P304+P340; P305+P351+P338; P312; P321; P332+P313; P337+P313; P362; P403+P233; P405; P501